Combination vs. disproportionation in dialkyl biradicals. Selectivity reversal in a crystalline solid.
نویسندگان
چکیده
While 1,6-biradicals produced by photodecarbonylation of dimethyl 11-oxodibenzo[c,h]bicyclo[4.4.1]undeca-3,8-diene-1,6-dicarboxylate (1) react exclusively by disproportionation in benzene solution, reactions in crystals lead to radical-radical combination reactions in almost quantitative yield.
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ورودعنوان ژورنال:
- Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology
دوره 5 5 شماره
صفحات -
تاریخ انتشار 2006